Crystal structure of catena-poly[N,N,N′,N′-tetramethylguanidinium [(chloridocadmate)-di-μ-chlorido]]
نویسندگان
چکیده
In the structure of the title salt, {(C5H14N3)[CdCl3]} n , the Cd(II) atom of the complex anion is five-coordinated by one terminal and four bridging Cl atoms. The corresponding coordination polyhedron is a distorted trigonal bipyramid, with Cd-Cl distances in the range 2.4829 (4)-2.6402 (4) Å. The bipyramids are condensed into a polyanionic zigzag chain extending parallel to [101]. The tetra-methyl-guanidinium cations are situated between the polyanionic chains and are linked to them through N-H⋯Cl hydrogen bonds, forming a layered network parallel to (010).
منابع مشابه
Synthesis, Crystal Structure and Antibacterial Evaluation of Di-μ-chlorido-bis({2-[(4-methoxyphenyl)- iminomethyl]pyridine-κ2N,N']Mercury(II)
New coordination polymer of [HgLCl2]n (1) with HgCl2 and Schiff base bidentate ligand (4-methoxyphenyl) pyridine-2yl methyleneamine (L) was prepared and structurally characterized. In the 1D network structure of 1, the mecury (II) ion adopts an HgN2Cl3 distorted square pyramid geometry. In this complex, one of the chlorine acts as bridging ligand connecting two adjacent mercury(II) ions while, ...
متن کاملcatena-Poly[[bis(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[bis(1-ethyl-1H-imidazole-κN 3)cadmium]]
The asymmetric unit of the crystal structure of the title compound, [Cd(2)Cl(4)(C(5)H(8)N(2))(3)](n), contains two Cd(II) cations, three 1-ethyl-1H-imidazole ligands, and four Cl(-) anions. The two Cd(II) atoms have quite different coordination environments: one is octa-hedrally coordinated by four Cl atoms and two N atoms from two 1-ethyl-1H-imidazole ligands, and the second is in a severely d...
متن کاملcatena-Poly[[bis(pyrazine-2-carboxamide)mercury(II)]-di-μ-chlorido]
In the polymeric title compound, [HgCl(2)(C(5)H(5)N(3)O)(2)](n), the Hg(II) atom (site symmetry ) adopts a distorted trans-HgN(2)Cl(4) octa-hedral coordination geometry. In the crystal, adjacent mercury ions are bridged by pairs of chloride ions, generating infinite [100] chains, and N-H⋯O and N-H⋯(N,N) hydrogen bonds help to consolidate the packing.
متن کاملThe diselanylbis(1,3-dimethyl-1H-imidazol-3-ium) dication stabilized by the polymeric catena-pentachloridotricuprate(I) anion.
In the title compound, catena-poly[diselanylbis(1,3-dimethyl-1H-imidazol-3-ium) [μ(3)-chlorido-tetra-μ(2)-chlorido-tricuprate(I)]], {(C(10)H(16)N(4)Se(2))[Cu(3)Cl(5)]}(n), the diselenide dication is stabilized by catena-[Cu(3)Cl(5)](2-) anions which associate through strong Cu-Cl bonds [average length = 2.3525 (13) Å] to form polymeric chains. The polymeric [Cu(3)Cl(5)](2-) anion contains cryst...
متن کاملcatena-Poly[(S)-2-methylpiperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]]
In the crystal structure of the title compound, {(C(5)H(14)N(2))[BiCl(5)]}(n), the Bi(III) cation is coordinated by six Cl(-) anions in a distorted octa-hedral geometry. Two Cl(-) anions bridge neighboring Bi(III) cations, forming a zigzag polymeric chain along the a axis. The discrete methylpiperazinediium cation adopts a normal chair conformation and is linked to the polymeric chains by N-H⋯C...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 72 شماره
صفحات -
تاریخ انتشار 2016